Comparative resin kinetics using in situ fluorescence measurements.
نویسندگان
چکیده
The aminolysis of a novel activated ester resin was utilized for kinetic study via continuous in situ fluorescence measurements. A variety of resin compositions (polystyrene, JandaJel, ArgoPore, TentaGel, NovaGel, and PEGA) and solvents (dimethylformamide, acetonitrile, tetrahydrofuran, 1,2-dichlorethane, and toluene) were tested to compare their effects on the reaction rate. A linear relationship between the reaction rate and (solvent polarity x swelling of resin) was elucidated for the aminolysis reaction.
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ورودعنوان ژورنال:
- Journal of combinatorial chemistry
دوره 4 3 شماره
صفحات -
تاریخ انتشار 2002